Wednesday, October 30, 2019
Human Trafficking Research Paper Example | Topics and Well Written Essays - 2000 words - 1
Human Trafficking - Research Paper Example Human trafficking is an important issue to discuss since most governments have not been serious with the vice. There are many arguments that have been put forward to attempt to explain how human trafficking started. There are some sources that claim that slave trade started when Africans were being captured by slave traders and would be shipped across Atlantic Ocean to America. Some consider the forced labor of children in 1700s was the true commencement of human trafficking. There was also white slavery that some individuals consider it to be the first legally recognized form of human trafficking. Complexities of the phenomenon, as well as opposing views about prostitution, have resulted in many controversial debates on human trafficking. The origin of human trafficking debates started towards the end of the nineteenth century during that time ââ¬Å"white slaveryâ⬠resulted in public outrage and was a key priority for international organizations. ââ¬Å"White slaveryâ⬠is the abduction as well as transportation of white women for purposes of prostitution (Masika 22, and Pliley 18 1). White slaves were women and girls who were unsuspectingly ensnared into prostitution through being seduced or raped when drunk or drugged, whence they were ââ¬Å"enslavedâ⬠in whore houses. This problem was addressed through the formulation of regulations that stopped human trafficking. Human trafficking is a concern that plagues our society. Human trafficking is a great threat to state security and source of insecurity to the vulnerable and affected communities and individuals (Beeks and Amir xv, and Quayson and Arhin 5). For states, human trafficking is a key challenge to their legitimacy, authority, as well as control over sovereign territory as well as state borders. Human trafficking thrives profligately on corruption since human traffickers use links with state officials,
Monday, October 28, 2019
Sherlock Cannot be Taken Seriously in Brazil Essay Example for Free
Sherlock Cannot be Taken Seriously in Brazil Essay Amelia Simpsonââ¬â¢s introduction to Detective Fiction from Latin America argues that Latin American culture, including its citizensââ¬â¢ pervasive distrust of law and authority, has inhibited its authors from creating a large body of original detective novels. Though these detective works are quite popular with Latinos, the novels must usually be set in countries with strong democratic values and justice systems for them to seem authentic. The people of Brazil, Cuba and other autocratic countries, where authority is feared from birth and laws and police are harsh tools of oppression, are skeptical of fair, justice-minded detectives thwarting criminals. If a detective novel follows the traditional, rigid, classical form, it will seem unrealistic to Latinos. The more contemporary ââ¬Å"hard-boiledâ⬠detective novel, with its harsher portrayal of societies that are deeply flawed and teeming with injustice and evil, is a much better fit into the world view of Latin Americans. Within these increasingly popular works, imperfect societies and behaviors can be revealed, examined and utilized within the detective novel template. The classical detective genre, with its ââ¬Å"reassuring view of society,â⬠its ââ¬Å"detached, gentlemanlyâ⬠sleuths, and its clear, fair delineation between good and evil begs skepticism from Latin American readers who find those concepts foreign and unrealistic. These oppressed citizens of ââ¬Å"predatory hegemoniesâ⬠can only accept the democratic precepts of law and order and justice when the classical detective work is set in a plausible setting like America. These relatively simple, predictable, rigid ââ¬Å"whodunitsâ⬠have been read and enjoyed by Latino masses, but ironically, Latino authors have not reflexively rushed to quench the market for more classical detective novels. The evolution of the classical version to the ââ¬Å"hard-boiledâ⬠detective novel that often ââ¬Å"reveals a corrupt and violent society,â⬠is more logically embraced by Latin American mystery readers. The ââ¬Å"hard-boiledâ⬠model incorporates ââ¬Å"distrust of institutions and its view of crime as all-pervasive. â⬠If viewed as a continuum, the classical version is simple and predictable while the hard-boiled is chaotic and more difficult to predict. The classical version uses traditional, stable values of fair justice, while the ââ¬Å"hard-boiledâ⬠relies on environments filled with turmoil and corruption. The classical genre is rigid, and itââ¬â¢s accepted that ââ¬Å"laws are laws. â⬠Therefore, boundaries are abundant, and good is expected to prevail over evil. Conversely, the ââ¬Å"hard-boiledâ⬠version removes most societal boundaries and its setting is likely to be ââ¬Å"a model of skepticism and failure, of a lost utopia. â⬠This harsh worldview melds more realistically into the somewhat bleak, dictatorial environment that many Latinos encounter from birth. Thus, Latinos are predisposed to accept the more contemporary, ââ¬Å"hard-boiled,â⬠detective novel. Feelings and portrayals of optimism versus pessimism also set the classical detective genre apart from the ââ¬Å"hard-boiledâ⬠type. America, with its history of freedom and stability and its strong sense of law and order, provides a stable, hopeful environment for the gentlemanly detective. He is free to ply his trade, systematically and fairly plodding to a just resolution of the crime. A predictable, step-by step, picture can be portrayed with a ââ¬Å"mechanistic crime-to-solution sequence. â⬠On the other hand, Latin Americans are better able to grasp the ââ¬Å"hard-boiledâ⬠genre where chaos, evil, oppression and injustice thrive. For many Latinos, ââ¬Å"the law is feared and, whenever possible, violated. â⬠They live in a police state and they ââ¬Å"breathe and sweat repression. â⬠This way of life, with fear and suspicion as mainstays, allows ââ¬Å"hard-boiledâ⬠detective authors to insert hazier motives for oppressed perpetrators who may become criminals out of necessity. The dark, pessimistic ââ¬Å"triumph of the criminal over societyââ¬â¢s lawsâ⬠can seem natural in a hard-boiled work, but would certainly not fit in the classical detective novel template that relies on optimism, justice and sure punishment for the criminal who is pursued and captured by the persistent, reasonable sleuth. The advent of the ââ¬Å"hard-boiledâ⬠detective novel seems to open the field for Latin American authors to give their countrymen the mysteries that they enjoy and desire. This change has not come quickly. As recently as 1983 the Brazilian author, Correa, observed that ââ¬Å"Brazilian detective literatureâ⬠¦with its own, national characteristics, doesnââ¬â¢t exist. â⬠In the same vein, it took more than half a century for the 1929 ââ¬Å"hard-boiledâ⬠novel, The Maltese Falcon, to become the best-selling detective novel of 1984 in Brazil. The conservative, rigid classic has finally given way to the contemporary detective novels with their critical societal views that play realistically and believably in Latin America. Sherlock Holmes, while somewhat entertaining and quite competent, is a relic who cannot fit into the world view of Latin Americans. This classical detective has his limitations and his setting must have boundaries of law and order and benevolent justice. But Latinos can readily embrace and believe flawed, even malevolent sleuths who track criminals in settings where lawlessness and evil are the norm. Thus, Latin American authors have much more latitude and potential for success with their native audiences when they compose ââ¬Å"hard-boiledâ⬠detective novels. This multi-faceted, contemporary detective genre allows societal flaws to be acknowledged and exploited for the entertainment and intrigue of Latin American readers.
Saturday, October 26, 2019
McDonaldization :: essays research papers
sociologist George Ritzer argues that the relationship between McDonaldââ¬â¢s and our society runs even deeper. Beyond its commercial propaganda and symbolism, Ritzer says, McDonaldââ¬â¢s is a potent manifestation of the rational processes that define modern society. Ritzer warns that the spread of such "rationalized systems" has had irrational consequences, not least of which is the "disenchantment of the world," a situation in which rationality takes over, leaving no room for the mysterious, unpredictable qualities that make us human. Ritzerââ¬â¢s scholarly work has been heavily influenced by German sociologist Max Weber, who feared that bureaucracy would spread until society became a seamless web of rationalized institutions from which there would be no escape. At the time when Weber wrote, in the early twentieth century, totalitarianism was the biggest threat to individual freedom. In the 1980s, Ritzer thought to apply Weberââ¬â¢s theories about rational systems to a very different threat: the proliferation of fast-food chains. When Ritzer began writing and talking about the dangers of "McDonaldization," he struck a nerve: some agreed with him, but many others rushed to defend the pop-culture institution. He went on to write a social critique on the subject, applying sociological theories to the culture in a way that lay readers would understand. The McDonaldization of Society (Pine Forge/Sage Publications) was successful enough that he wrote several follow-ups, including The McDonaldization Thesis and Enchanting a Disenchanted World (both Sage Publications). Ritzerââ¬â¢s most recent book is Explorations in the Sociology of Consumption: Fast Food, Credit Cards, and Casinos (Sage Ltd.). In addition to writing about sociology for a general audience, he teaches at the University of Maryland, where he is a distinguished professor with numerous academic awards and volumes to his credit. We met for this interview on a beautiful fall day at Ritzerââ¬â¢s home in Maryland. A breeze blew outside, picking up red and yellow leaves and twirling them across the grass while we sat inside discussing the disenchantment of the world. Jensen: What is "McDonaldization"? Ritzer: Itââ¬â¢s the process by which the principles of the fast-food industry -- efficiency, predictability, calculability, and control through technology -- are being applied to more and more sectors of society in more and more parts of the world. Predictability: An Egg McMuffin in New York will be the same as an Egg McMuffin in Chicago. Customers can expect no surprises, neither pleasant nor unpleasant. Workers, too, behave in predictable ways. Those who interact with customers have actual scripts to follow.
Thursday, October 24, 2019
Las 432 â⬠Genetically Modified Foods Essay
It has been determined that GMOââ¬â¢s are made up of plants, animals, viruses and bacteria that are created in laboratories. Scientist started experimenting with GMOââ¬â¢s in the early 1950ââ¬â¢s with investigation of plants DNA. In the 1970ââ¬â¢s scientist developed the first genetically engineered organism. By the early 1990ââ¬â¢s biotechnology had expanded on production of GM foods to the public, but this brought fourth concerns. There are also those who believe that the laws and regulations that are attributed to genetically modified foods have been influenced through both the media and political aspects. These influences have brought about worries to GM food consumers and they started comparing the similarities and differences in organic foods and GM foods. Consumers want to know what GM food products they have consumed and will be aware of any affects that may be acquired with consumption. Not only are there consumer challenges that must be faced with these technological experimentations, but also the impacts that may be developed environmentally or effects that may incur with nature and wildlife. Some societies are worried about how the rich will prosper and the poorer countries will suffer and possibly go hungry. Some religions and groups protest eating genes and do not want to consume such un-natural foods and other concerns still the unknown effects on human allergies and transfer of antibiotic resistance to intestine bacterial flora or pathogenic bacteria in our bodies. Genetically Modified Organisms in Food Thesis: Consumers today have a right to know if genetically modified foods are harmful to our health, the environment and our economy. In order to be able to answer these questions more research needs to be done. Summary Controversy around genetically modified foods is becoming big news and sorting through volumes of information can be intimidating. The public is asking a lot of questions about GM foods and they are also raising concerns about the effects these foods may have on their health or the environment. There are different advantages and disadvantages of GM foods, although to what extent they can help or harm humans and the environment is a debatable aspect of this technology. The time has come to look at the decisions that we make about genetic engineering in food crops and if it will have permanent consequences on our food production capacity. Are genetically modified foods putting us at a crossroads in terms of the agricultural legacy that we will leave behind for our children and grandchildren? Modern technology has given us the ability to go beyond selective breeding. Organisms can now be modified by moving genes from one species to another and by introducing synthetic genetic material into their genomes. Humans no longer simply select from variations present in the population: they create new variations! Some find our new power exciting. They dream of crops with greater resistance to disease and insect pests, pigs with healthy fats, and a level of agricultural production sufficient to feed everyone on the planet. Others fear that we have crossed an important boundary and are now tinkering with living systems that we understand incompletely. They question our ability to predict the consequences of our actions and are afraid that we may disrupt the delicate natural order. GMO Technology I. What Are GMOs? GMOs (genetically modified organisms) are plants, animals, viruses and bacteria that are created in the laboratory. Their DNA (genes) has been modified through the use of gene splicing techniques in a desire to create ââ¬Å"newâ⬠organisms. The technology involves removing the DNA of one species and inserting it into another species, resulting in new and different varieties of plant, animal, viral and bacterial genes which donââ¬â¢t naturally occur in nature or by hybridizing (Smith, 2012, para. 7). Other names for the technology are ââ¬Å"modern technology or gene technology,â⬠genetic engineering or recombinant DNA technology, and biotechnology (World Health Organization (WHO), 2012, para. 2). GMOs are used to create genetically modified plants which in turn are used to create genetically modified crops for human consumption and as animal feed. Developers believe that producers and consumers would be interested in these foods due to their ââ¬Å"built-inâ⬠advantages of lower prices, high nutritional value and hardiness. The desire is to achieve crops that are resistant to spoilage, drought, insects and herbicides. At the outset genetically modified (GM) seed manufacturers envisioned their product being used by producers, thus they focused on innovations those farmers, and more generally the food industry, would accept and appreciate (WHO, 2012, para. 3). WHO states that (2012), the initial objective for developing plants based on GM organisms was to improve crop protection. The GM crops currently on the market are mainly aimed at an increased level of crop protection through the introduction of resistance against plant diseases caused by insects or viruses or through increased tolerance towards herbicidesâ⬠(para. 4). Commodity crops were the First Generation GM crops and included soybean, maize/corn, cotton, canola and sugar beets (Schonwald, 2012, p. 26). GM soybeans and canola have permeated the market and can be found in most processed foods, e.g. , spaghetti, candy Schonwald, 2012, p. 25). There was expectation that with the success of first generation crops, biotech specialty crops (produce) would follow, focusing more on consumer tastes. According to Kent Bradford, director of University of California (UC) at Davisââ¬â¢s Seed Biotechnology Center (2012), ââ¬Å"these crops hadnââ¬â¢t been commercialized since 1998â⬠(Schonwald, 2012, p. 26). The author wondered why, and so enlisted the assistance of Kent Bradford for answers on ââ¬Å"what was going on with bioengineered specialty cropsâ⬠(Schonwald, 2012, p. 26). Bradford and a collaborator, Jamie Miller, found that research on specialty crops was underway and had never ceased. The research involved input traits that are important to agriculture such as ââ¬Å"disease resistance,â⬠ââ¬Å"insect resistance,â⬠ââ¬Å"adaptability to certain environmentsâ⬠and output traits that ââ¬Å"improve taste and texture and could lead to changes in the dining experience of the futureâ⬠(Schonwald, 2012, p. 26). Schonwald says Bradford contends that (2012), ââ¬Å"There was research on 46 different species with more than 300 traits being testedâ⬠(p. 26. ). So things were going on at the research level, but the results were not moving forward. Bradford found this was due to regulatory controls. Because of the lack of consumer confidence in transgenic breeding the regulatory process for genetically modified foods was much different than for non-GMO foods. In contrast, foods using classic breeding processes were considered safe for consumption. But GMO foods were ââ¬Å"guilty until proven innocentâ⬠(Schonwald, 2012, p. 26). Schonwald reports that (2012), ââ¬Å"A genetically engineered crop must pass review by the U. S. Department of Agriculture (USDA), the Environmental Protection Agency, and the Food and Drug Administration before it is commercialized. The cost could range from $50,000 to tens of millions of dollars to win regulatory approval. For every ââ¬Å"transgenic event,â⬠the genetic engineer must show exactly what genes went into the plant and how they function, and then prove how the plant makeup has been altered. That research is costly. So is plant storage. Once a transgenic creation is spawned at the Plant Transformational Facility, it is whisked to the UC Davis Controlled Environment Facility, where it will stay in a tightly secured warehouse. Or it will be airmailed to some other place, where it will live out its life in another intensely biosecure environment. The process is costly and time-consuming, which partly explains why biotech crop development is largely in the hands of the agribusiness giants ââ¬â the Monsantoââ¬â¢s, Syngentaââ¬â¢s, and Bayer Crop Sciences of the worldââ¬âwho have the resources to undertake the process. With such high approval costs, big companies have favored commodity crops with market potential for hundreds of millions of dollars to sales, not tens of millionsâ⬠( p. 26) According to Bradford, non-governmental organizations ââ¬â Greenpeace and the Union of Concerned Scientists ââ¬â were responsible for the stringent governmental handling of the biotech specialty crops. The $20 million organic foods industry labored to stop the proliferation of GMO foods. They did so by launching a campaign against GMOs, inundating the USDA with thousands of letters (ââ¬Å"275,026 to be exactâ⬠) expressing anti-GMO sentiments. This led to the non-inclusion of GMO foods under the USDAââ¬â¢s standards of organic produce (Schonwald, 2012, p. 27). U. S. Leads in Biotech AgricultureMore than 170 million acres of biotech crops are under cultivation in the United States, more than twice Brazilââ¬â¢s acreage, which ranks second. Experts credit faster technological advances, more lenient regulations and expanding economic benefits for the U. S. lead. Biotech acreage by Country, 2011| Country| Acres (in millions)| Biotech crops| United States| 170. 5| Corn, soybean, cotton, canola, sugar beet, alfalfa, papaya, squash| Brazil| 74. 9| Soybean, corn, cotton| Argentina| 58. 6| Soybean, corn, cotton| India| 26. 2| Cotton| Canada| 25. 7| Canola, corn, soybean, sugar beet| China| 9. 6| Cotton, papaya, poplar, tomato, sweet pepper| Paraguay| 6. 9| Soybean| Pakistan| 6. 4| Cotton| South America| 5. 7| Soybean, corn, cotton| Uruguay| 3. 2| Soybean, corn|. Source: Clive James, ââ¬Å"Global Status of Commercialized Biotech/GM Crops: 2011,â⬠International Service for the Acquisition of Agri-Biotech Applications, 2011, p. 2, www. isaaa. org/purchasepublications/itemdescription. asp? ItemType=BRIEFS&Control=IB043-2011| (McClure, 2012, p. 724) Below is a list of tips on how to say no to GMOs: Tip #1: Buy Organic Certified organic products cannot intentionally include any GMO ingredients. Buy products labeled ââ¬Å"100% organicâ⬠ââ¬Å"organic,â⬠or ââ¬Å"made with organic ingredients. â⬠You can be doubly sure if the product also has a Non-GMO Project Verified Seal (see next tip). Tip #2: Look for Non-GMO Project Seals Products that carry the Non-GMO Project seal are independently verified to be in compliance with North Americaââ¬â¢s only third party standard for GMO avoidance, including testing of at-risk ingredients. Tip #3: Avoid At-Risk Ingredients Even if itââ¬â¢s not labeled organic or verified non-GMO, you can still avoid products made with ingredients that are likely derived from GMOs. The eight most common GM food crops are: *Corn (as in corn oil, cornmeal, cornstarch, and other corn-based ingredients) *Soybeans (as in soybean oil, soy protein, soy lecithin, soy milk, tofu, and other soy-based ingredients). *Canola (as in canola oil) *Sugar beets (the ââ¬Å"sugarâ⬠listed on food labels is almost always derived from sugar cane and GM sugar beets) *Most Hawaiian papaya *A small amount of zucchini and yellow squash *Also, beware of dairy products, which may come from cows injected with GM bovine growth hormone, and meats from animals (including farmed fish) that have been fed GM foods. [Instead] look for dairy products labeled No rBGH or rBST, artificial hormone-free, or organic; wild-caught fish; and meat labeled organic or 100% grass-fed. Tip #4: Use Non-GMO Shopping Guides. Download either the new Non-GMO Shopping Tips brochure or Non-GMO Shopping Guide at www. nongmoshoppingguide. com; in order to help identify, avoid GM foods and find hidden GM ingredients on food labels. If you have an iPhone, download the ShopNoGMO guide for free from the iTunes store. Copyright of Better Nutrition is the property of Active Interest Media, Inc. and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holderââ¬â¢s express written permission. However, users may print, download, or email articles for individual use (Smith, 2012, p. 14). II. Scientific Techniques and Experiments Various techniques are used to transfer DNA genes into the host cell. Researchers have been perfecting these techniques over the past 40 years. In one technique, target cells are bombarded with heavy metals coated with the gene transferred have been bombarded. Yet another technique transfers genes by using a naturally occurring bacterium along with a pulse of electricity to introduce genes into the targeted cell (McClure, 2012, p. 720). According to McClure (2012), Opponents of GM foods argue that the public should be informed of the techniques used in gene-transferring (p.720). At the Plant Transformation Facility at the UC, Davis more than 15,000 transgenic events have occurred. Transgenic event is the molecular biologists way of describing the blasting of DNA from one life form into another. This building, a short distance from the student union, houses thousands of Petri dishes of microscopic plantlets bathing in pink and fluorescent blue lights. Here biologists use a gas-pump-like tool called the Helium Particle Delivery system to mix sexually incompatible species together. They use gold bullets (literally) to fire genes from one species into another in a bombardment chamber. As a result the ââ¬Å"Davis lab has birthed grapes spiked with jellyfish, tomatoes spiked with carp, transgenic squash, transgenic carrots, and transgenic tomatoesâ⬠(Schonwald, 2012, p. 25). In Changing Genes to Feed the World, David Pimentel takes a look at one molecular biologistââ¬â¢s account of plant breeding and the field of genetic engineering of crops. In her book, Mendel in the Kitchen, author Nina Fedoroff compares the contributions of genetically engineered plants with that of early plant breeding research, e. g. , development of hybrid corn, achieved through the transfer of genes within the confines of crop species. This method contributed greatly to the growth of crop yields during the Green Revolution. Specifically, according to Fedoroff (2004), traditional methods of cross breeding were responsible for, ââ¬Å"40 percent of the increase in yields. The remaining 60 percent was due to greater inputs in fossil-fuels energy, fertilizers and pesticidesâ⬠(Pimentel, 2004, paras. 1-2). Crop yields increased greatly during the years 1950-1983. Globally, 80 percent of the calories consumed by humans came from grains, making the Green Revolution an important feeding mechanism for billions of people around the world (Pimentel, 2004, para. 2). Though the use of traditional breeding methods greatly increased the yield and quality of crops, these methods were quite slow, in comparison to the advances being made in the field of molecular biology and genetic engineering. Before, breeders were required to manually manipulate genetic material within a specific crop to increase yields. Now, through genetic engineering, genes can quickly be transferred from one plant species to another and brought into crops (Pimentel, 2004, para. 3). As more and more genetically modified foods are being integrated into our food systems, there is a need to be able to detect their presence in food products in order to determine if food manufacturers are in ââ¬Å"compliance with labeling requirementsâ⬠(Yi, Yien-Chian, Foo-Peng Lee, and Nam-Trung, 2009, para. 1). There is a method that allows for the rapid detection of the presence of GMOs in foods and it is called ferrofluid-driven PCR microchip. ââ¬Å"The microchip was fabricated in polymethyl methacrylate by CO? laser ablation and was integrated with three temperature zones. PCR solution was contained in a circular closed micro channel and was driven by magnetic force generated by an external magnet through a small oil-based ferrofluid plug. Successful amplification of genetically modified soya and maize were achieved in less than 13 minutes. This PCR microchip combines advantages of cycling flexibility and quick temperature transitions associated with two existing microchip PCR techniques, and it provides a cost saving and less time-consuming way to conduct preliminary screening of GMOsâ⬠(Yi, Yien-Chian, Foo-Peng Lee, & Nam-Trung, 2009, para. 1). History of GMOââ¬â¢s I. Biotechnology Chronology ââ¬Å"1950s ââ¬â 1960s: Scientists identify genes and begin investigating the role of DNA in plant development. 1953-American biochemist James Watson and British biophysicist Francis Crick describe the structure of DNA, setting the stage for mapping the genetic code. 1967-Lenape potato, a new variety bred for making potato chips is withdrawn from experimental production after high levels of toxin are found. 1970s ââ¬â 1980s: Scientists begin experimenting with genetic transformation of plants and animals. 1973-Scientists create first genetically engineer organism. 1983-Researchers transfer new DNA into plants, leading to the creation of genetically modified crops. 1989-Calene Inc. receives U. S. patent for gene sequence in GM Flavr Savr tomato. 1990s: Biotech foods are marketed to the public despite environmental and health concerns. 1992-FDA decides not to require labeling of most GM foods, sparking mistrust of the technology. 1993-FDA allows cows to be injected with bovine growth hormone (rBGH) made from genetically modified bacteria, setting off consumer protests. 1994-FDA approves Flavr Savr tomato, first GM food approved for sale to consumers. 1996-Monsanto introduces Roundup Ready soybeans, first of several popular herbicide-tolerant or insecticide-producing crops. 1998- European Union (EU) halts approvals of new GM crops in what is termed an ââ¬Å"unofficial moratorium. â⬠2000s: Genetically engineered foods face continued criticism despite growing scientific consensus that they do not pose greater safety risks than conventional crops. 2000-Bowing to international demands, U.S. officials agree to label GM commodities for exportâ⬠¦. Weeds resistant to Roundup discovered in Delawareâ⬠¦. Friends of the Earth, a major environmental group, reports that genes from StarLink corn, a GM crop approved only for animal consumption, have been discovered in taco shells. The discovery prompts recalls of corn products and lawsuits, but researchers are unable to document any human health effectsâ⬠¦. Centers for disease Control study concludes StarLink did not cause allergic reactions claimed by 28 people. 2002-National Center for Food and Agricultural Policy finds that GM crops in the United States produced four billion pounds of additional foods and fiber on the same acreage, improved farm income by $1. 5 billion and reduced pesticide use by 46 million poundsâ⬠¦. Monsanto announces it will delay introduction of GM wheat amid concerns from farmers that it will harm exports. 2003-Bollworms resistant to the Bt toxin, an insecticide produced by GM cotton, discovered in the South. 2004-Under U. S. pressure, EU drops de facto ban on GM crops but institutes mandatory labeling; many European stores wonââ¬â¢t stock GM foods because of consumer fears. 2008-Monsanto sells unit that produces rBGH, as major grocers including Wal-Mart, Publix and Kroger decline to sell milk from cows treated with the product. 2010-After approving the sale of GM eggplant, Indiaââ¬â¢s environment minister declares a moratorium on the product because of public outcry. 2011-GM crops are grown on 395 million acres of farmland globally, though more than 90 percent is in just three crops: soybeans, corn and cotton. 2012-Anti-GMO groups file petitions containing more than 1 million signatures demanding that the FDA require GM foods to be labeledâ⬠¦. Californian vote scheduled for Nov. 6 on ballot initiative requiring labeling for GM foodsâ⬠(McClure, 2012, p. 727). II. Advantages and Disadvantages The people of the United States (U. S. ) have been unknowingly consuming GMO foods since the 1990s. The Food and Drug Administration scientists warned that these new foods had the capability to produce new allergens and toxins and advised that more thorough testing was needed. But the U. S. governmentââ¬â¢s position was that GM foods were equivalent to non-GMO foods and failed to require labeling and testing (Smith, 2012, para, 9). According to the American Academy of Environmental Medicine (AAEM), eating GMO foods contributes to a number of health risks (Smith, 2012),ââ¬Å"including infertility, immune system issues, accelerated aging, disruption of insulin and cholesterol regulation, gastrointestinal issues, and changes in organsâ⬠(para. 9). AAEM reported that doctors most likely are seeing negative health effects in their patients and may not realize that GMO foods are the culprit. Doctors are urged to prescribe non-GMO diets for all of their patients (Smith, 2012, para. 9). The environment is not exempt from the risks of GMO foods. There is the threat of GMO seeds contaminating nearby fields of organic and non-GMO crops. Pesticide usage has dramatically increased over the first thirteen years since the GM crops were introduced. Further, high amounts of herbicide usage on GM herbicide ââ¬âresistant crops have caused the development of ââ¬Å"superweedsâ⬠that adapt to and withstand your typical herbicides (Smith, 2012, para. 10). On the positive side, genetic engineering offers a wonderful solution to farmers, especially those in developing countries, and that is the opportunity for developing perennial grains. As most grains are annual crops, tilling and replanting of the soil is required every single year. This involves an enormous amount of energy each year, including fossil and human energy and strength. Annual tillage also results in soil erosion. Planting perennial grains would mean that farmers would only need to till and replant every five or six years. This would be a major benefit for farmers in developing countries, as tilling for them involves 400 hours per hectare, hand-tilling their fields prior to planting their crops. As such, according to the author, ââ¬Å"plant breeding and genetic engineering will continue to make a tremendous contribution to our food supplyâ⬠(Smith, 2012, para. ). Other advantages of GM foods include disease resistance, cold tolerance, drought resistance, nutrition, pharmaceuticals, and phytoremediation (Whitman, 2012, pp. 2-4). Legal and Political Issues I. Regulations and Laws There have been an abundant number of studies done in the past on American health and safety standards that have demonstrated the inconsistencies of risk assessment. Some standards are rather strict and offer few or no benefits in savings lives, preventing diseases or injuries; while other standards have been negligent and have placed a considerable amount of lives at risk or harm. It is essentially due to the passage of these standards for which the American regulatory policy making has been implanted. In the past, both Congress and the political appointees who head regulatory agencies have been very susceptible to public opinion and public pressures. As a result, the more the American public is prone to worry about a particular risk, the more meticulous American policy-makers are likely to regulate it. ââ¬Å"Therefore, many of the American regulatory policies, especially those between the mid 1960s through the mid 1980s, were characterized by the triumph of ââ¬Å"passionâ⬠over ââ¬Å"sound science. â⬠(Vogel, 2001). In 1984, the Federal Government established a formal policy that is referred to as ââ¬Å"The Coordinated Framework for Regulation of Biotechnologyâ⬠. This policy describes the Federal system for evaluating products that have been developed using modern biotechnology. ââ¬Å"The Coordinated Framework is based upon health and safety laws developed to address specific product classes and involves the cooperation of three federal regulatory agencies; the EPA, the USDA, and the FDA. The U. S. Government has written new regulations, policies and guidance to implement these laws for biotechnology as products have developedâ⬠(United States Regulatory Agencies Unitied Biotechnology Website, 2012). EPA Regulation ââ¬Å"Under the Toxic Substances Control Act (TSCA), the EPA regulates the use of intergeneric microorganisms in commerce or commercial research. The EPA considers intergeneric microorganisms to be those formed from organisms in different genera (genera is the plural of genus, which is a level in a taxonomic classification system based on the relatedness of organisms) or those microorganisms formed with synthetic DNA not from the same genusâ⬠(Biotechnology Program under the Toxic Substances Control Act, 2012). ââ¬Å"The EPA believes that inter generic micro organisms have a sufficiently high likelihood of expressing new traits or new combinations of traits to be termed ââ¬Å"newâ⬠and warrant EPA review. The Office of Pollution Prevention and Toxics (OPPT), Biotechnology Program conducts a screening program for new microorganisms under section 5 of TSCA. In 1997, the EPA published regulations that fully implement its pre-manufacture program for microorganisms under TSCA section 5. Prior to 1997; the EPA operated its biotechnology program in accordance with the 1986 Policy Statementâ⬠(Biotechnology Program under the Toxic Substances Control Act, 2012) USDA Regulation. | ââ¬Å"USDA supports the safe and appropriate use of science and technology, including biotechnology, to help meet agricultural challenges and consumer needs of the 21st century. USDA plays a key role in assuring that products produced using biotechnology are safe to be grown and used in the United States. Once these products enter commerce, USDA supports bringing these and other products to the worldwide marketplaceâ⬠(Bitechnology, 2012). | ââ¬Å"The Advisory Committee on Biotechnology and 21st Century Agriculture (AC21) was originally established in February, 2003 and first met in June, 2003. Under its Charter, the committee is charged with examining the long-term impacts of biotechnology on the U. S. food and agriculture system and USDA, and providing guidance to USDA on pressing individual issues, identified by the Office of the Secretary, related to the application of biotechnology in agriculture. The AC21 is a broad-based committee representing a wide range of interests and agricultural expertiseâ⬠(USDA Advisory Committee on Biotechnology & 21st Century Agriculture (AC21), 2012). FDA Regulation ââ¬Å"In the Federal Register of May 29, 1992 (57 FR 22984), FDA published its ââ¬Å"Statement of Policy: Foods Derived from New Plant Varietiesâ⬠. The 1992 policy clarified the agencyââ¬â¢s interpretation of the application of the Federal Food, Drug, and Cosmetic Act with respect to human foods and animal feeds derived from new plant varieties and provided guidance to industry on scientific and regulatory issues related to these foods (Genetically Engineereed Plants for Food and Feed, 2012). The 1992 policy applied to all foods derived from all new plant varieties, including varieties that are developed using recombinant deoxyribonucleic acid (rDNA) technology. This site refers to foods derived from plant varieties that are developed using rDNA technology as ââ¬Å"bioengineered foodsâ⬠â⬠(Genetically Engineereed Plants for Food and Feed, 2012). ââ¬Å"In the Federal Register of January 18, 2001 (the premarket notification proposal; 66 FR 4706), FDA issued a proposed rule that would require that developers submit a scientific and regulatory assessment of the bioengineered food 120 days before the bioengineered food is marketed. In the premarket notification proposal, FDA recommends that developers continue the practice of consulting with the agency before submitting the required premarket noticeâ⬠(Genetically Engineereed Plants for Food and Feed, 2012) The chief statutes under which the above agencies have been given regulatory or Review authority comes from the following Actââ¬â¢s: * The Federal Insecticide, Fungicide and Rodenticide Act (FIFRA) (EPA); * The Toxic Substances Control Act (TSCA) (EPA); * The Food, Drug and Cosmetics Act (FFDCA) (FDA and EPA); * The Plant Protection Act (PPA) (USDA); * The Virus Serum Toxin Act (VSTA) (USDA); * The Public Health Service Act (PHSA)(FDA); * The Dietary Supplement Health and Education Act (DSHEA) (FDA) * The Meat Inspection Act (MIA)(USDA); * The Poultry Products Inspection Act (PPIA) (USDA); * The Egg Products Inspection Act (EPIA) (USDA); and * The National Environmental Protection Act (NEPA)(Guide to U. S. Regulations of Genetically Modified Foods and Argricultural Biotechnology Products, 2001) II. Current Political Issues Genetically modified foods have been a concern for many people around the world. In the past Europeans have been the most vocal in their resistance to GM foods and crops, to the point that they have implemented strict labeling requirements for any genetically modified foods sold. In the absence of stronger health and safety data, many national governments across the world have taken steps to lessen the existence of GE food within their borders. ââ¬Å"In Europe, six nations (Austria, France, Germany, Greece, Hungary, and Luxembourg) have enacted bans on the cultivation and import of GE products, and nearly 50 nations worldwide require that all GE foods be labeled as suchâ⬠(Dahl, 2012). To date in the United State there have been no mandatory labeling requirements for genetically modified foods. However this may soon change, Americans are now starting to ask questions about what they are eating and suspicions about the health and environmental effects of biotechnology is now behind the demand that foods from genetically modified crops be labeled. The most recent labeling effort that has come to the fore front is the California ballot initiative Proposition 37 called ââ¬Å"The Right to Knowâ⬠. What is Proposition 37? The California ââ¬Å"Right to Knowâ⬠Genetically Engineered Food Act is easy: The initiative would basically require food that is sold in retail outlets to be labeled if it is produced through genetic engineering, and would not allow these products to be labeled as ââ¬Å"natural. â⬠Prop 37 allows companies 18 months to change their product labels, and allows for the GMO disclosure to appear wherever they choose on the packaging (Facts Yes on Prop 37, 2012). If this initiative passes, California will be the first state to require all foods that have genetically modified crops in them to be labeled. However, there is an opposing side to this Proposition. Those that are against Proposition 37 feel that by having to label all foods with genetically engineered crops would mean higher food prices due to the cost of re-package existing foods, recordkeeping, or companies being forced to switch to higher priced non-GM foods. The opposing side also states that it would add more government bureaucracy and taxpayers cost, and create frivolous lawsuits (Stop the Deceptive Food Labeling Scheme, 2012). This is one political debate that will have everyone on the edge of their chairs. III. What are the Possible Health Effects of GM Foods? With so many of our foods today now coming from GM crops, questions are now being asked if there is a health risk from GM foods. The problem is that unlike the safety evaluations that are required for the approval of a new drug, the safety evaluations of genetically engineered foods for human consumption has not been as strict. So what is known about possible health issues from the consumption of GM foods? Scientists from around the world have been complaining that a majority of the research that is being done about the possible side effects of GM foods for human consumption is being conducted by scientists that are associated with the biotechnology companies; the same companies that are selling the crops seeds. That and the fact that these studies are being done by the biotechnology companies tend to show that there are no health problems associated with eating GM foods. The problem is this is a one sided research study. One of the biggest problems that independent researchers are facing is that it is extremely hard to get GM seeds in order to conduct any type of research. These seeds can only be purchased through a licensed seed dealer and a technology licensing agreement must be signed stating that no research will be done on the seed; this includes any research attributed to health and environment. Scientists who have managed to do research on the health impacts of the GM seeds are often harassed, intimidated, and defamed by those with a strong interest in the GM technology. Even with these challenges researcher have managed to conduct medical research on the health effects of GM seeds; of these tests the most obvious concern has been the risk of allergic reactions.
Wednesday, October 23, 2019
St. Johns River, North Florida
The St. Johns I have had many experiences with the St. Johns River in my life. For as long as I can remember I have lived less than a mile from this river. Every activity from boating, to canoeing, or fishing I have done in the river, and every time the water has seemed clean. Over the years the St. Johns River has acquired a bad reputation for being nasty or dangerous. Anything from flesh eating bacteria from algal blooms to bull sharks have been rumored to be lurking in its waters. Though some of these rumors are true and some of them are false, one will not die upon touching the water. However, the St.Johns does need some extra attention based on tests, past and current programs, and the fish population. Many tests performed on the river reflect that the water is relatively clean. State officials over Volusia and Seminole counties have noticed that there is the potential for a water shortage in the next couple years due to population increases. If nothing is done, the ground water in this area will run out. A plan is being proposed to use surface water from the St. Johns River to supplement the ground water. State officials believe they can filter the water from the St. Johns of bacteria and use this water for drinking water. Ann Givens) The fact that the state is considering using the water in the St. Johns for drinking water shows that the water quality is good. If there were severe algal blooms, the state would not consider trying to filter the water. Many tests performed on the river are in response to the paper mills present on the river. There is one mill in particular addressed on Rice Creek outside of Palatka. The waste water from these paper mills is dumped from pipes into the river. Ten years ago these mills were forced to upgrade their equipment due to a toxin being released called Dioxin.Dioxin is chemical that can cause cancer produced by the chlorine reactions in the mill. The older equipment was believed to be allowing this toxin to flow into the St. Johns River. Two years ago another test was done on the Rice Creek and traces of Dioxin are still present. The general belief is that Dioxin has remained in creek residue. (Patterson, S. ) Tests similar to this are done throughout the river. The residue remaining from the Dioxin is only present in Rice Creek and is not present throughout the water system. This effort to control the Dioxin shows progress.Scientists identified that the Dioxin was present and the source and took severe action to eliminate the expansion of Dioxin. Though this effort was necessary and applauded, efforts now need to be made toward eliminating the remaining residue and removing Dioxin from the river completely. Many programs and funds have been devoted to improving the water of the St. Johns River. A major act proposed in the 1970ââ¬â¢s was the Clean Water Act of 1972. The Clean Water Act forced Floridians to find bodies of water that are impaired due to higher nitrogen levels.Once established, the state had to institute total maximum daily loads for each of these bodies of water. The total maximum daily load (TMDL) is established ââ¬Å"based on the maximum amount of pollutant that the water body can assimilate without exceeding water quality standards. â⬠( Lynette, M. ) This act made progress in reducing the level of nitrogen being added in the river. Though this act passed in 1972 the problem is still present. Over the years, Florida has seen 80,000 acres of its wetlands developed. (Littlepage, R. L. This results in less water present in the system and more nitrogen in the ground water from people fertilizing their yards. If the population in central Florida continues to expand and the wetlands continue to disappear, the presence of algal blooms and the reduction of the fish population will never stop. The water removed and nitrogen added will continue to create a steeper imbalance. Also with development, central Florida is trying to take water from the St. Johns f or drinking water for their excessively large population.This will just make the nitrogen to water imbalance even steeper. Rules and regulations need to ether be put on wetlands destruction, fertilizer use, and population limits in central Florida based on how many people their water supply can sustain. In 2006 a large sum of money was devoted to the effort of preserving the St. Johns River. Twenty seven million dollars was devoted to reducing the amount of nutrients, like nitrogen, entering the river and increasing standards for companies like Jacksonville Electrical Authority (JEA) who dump into the St. Johns River.The mayorââ¬â¢s office made JEA increase its standards for dumping waste water into the river and expand its programs for reusing water. This would reduce the amount of waste water dumped in the river and reduce the amount of harmful chemicals that enter the river from the JEA plant. (Littlepage, R. L. ) A major concern in the St. Johns is the fish population. The la rgest pollutant in the river is nitrogen from excess fertilizers that flow into the groundwater and into the river. The plant life of the river feed on this nitrogen. More nitrogen then leads to more plants.As the plant population increases problems such as algal blooms on the surface of the water occur. With the algal bloom situation the lower section of the water is blocked or partially blocked from sunlight. This leads to less plant life on the floor of the river and thus less oxygen in the water. With the lack of oxygen the fish population will plummet soon after. In 1994, an experienced bass angler by the name of Doug Gilley did an interview for the Orlando Sentinel. In this article he provided his professional insight on the change destruction of the bass population from 1984 to 1994.Ten years before this article was written, it would be no surprise for him to catch ââ¬Å"10, 20 or even 50 fish in a day. â⬠(Wilson, D) Doug was not the only one who had noticed this drast ic decrease in the bass population. State fisheries agreed with him. They have noticed that the ââ¬Å"large bass almost have disappeared from the river and that the number of mid-sized bass are declining. â⬠(Wilson, D. ) I personally have noticed the decline of fish from the river. My brother and I are avid fisherman and enjoy fishing for just about anything.We lived a quarter of a mile from the river so often we would take my grandfatherââ¬â¢s bass boat and go fishing in the river. However, no matter how much we prepared, we would never catch more than maybe one or two fish. This change shows how all the different pollutants are having a large impact on the fish population and if action is not taken species like the largemouth bass could be eliminated from the river. Fishing is not the only recreational activity that takes place in the St. Johns. Activities such as skiing and tubing take place daily during the spring and summer months.These are essential for Floridaââ¬â ¢s economy. When people are going out in their boats, many aspects of the economy are helped. People must buy gas for their boat, food to eat while they are on the boat, and other items. This also attracts tourists. By my house at a local marina, every summer they hosted a wakeboard camp for people to come learn how to wake board. Hundreds of people would come to learn how to wakeboard and have fun in the water. These people bought many things during their stay thus boosting the Florida economy. However, if the water is not maintained and kept clean, events like these cannot occur.Tourists would not be willing to get in the water and would take their business elsewhere thus restricting north Floridaââ¬â¢s economy. In closing, the St. Johns River is not dangerous as far swimming and boating are concerned but there are pollutants being dumped into the river that need to be addressed or eliminated. If nothing is done, based on tests done on the water, past and current programs, and the fish population the wildlife, the quality of the St. Johns will continue to plummet. The river damage will become impossible to fix and potentially impossible to swim or use for any recreation.The repercussions of this would be exponential. Water shortages could occur along with Jacksonville losing its appeal as somewhere to live. Citations Page Ann Givens of The Sentinel Staff. (2001, Feb 16). St. Johns River may slake our thirst the St. Johns water district plans to process river water in a three- year test to see if it can be made drinkable. Orlando Sentinel. Lisenby, L. (2007, Jul 11). Growth must be controlled to protect the St. Johns River. Florida Times Union. Littlepage, R. L. (2006, Jan 10). St. Johns Riverââ¬â¢s health deserves major effort.Florida Times Union. Lynette, M. M. , John, R. W. , & K, R. R. (2004). Nitrogen and phosphorus flux rates from sediment in the lower St. Johns River estuary. Journal of Environmental Quality, 33(4), 1545-1555. Patterson, S. (201 0, Aug 10). With mill pipeline still in doubt, old dioxin haunting rice creek research: Traces of a cancer-causing substance could still exist and be funneled into the St. Johns River. McClatchy ââ¬â Tribune Business News. Wilson, D. (1994, Sep 09). Veteran angler says bass fishing on St. Johns River deteriorating. Orlando Sentinel.
Tuesday, October 22, 2019
The Natural Behavior of Wolves
The Natural Behavior of Wolves Introduction Wolves belong to the broad class of the carnivorous animals. They belong to the Canidae family and thus, they are related to other carnivores like dogs and cats (Harrington, Fred, and Paul 263). No wonder their physical appearance is similar to that of the dogs.Advertising We will write a custom term paper sample on The Natural Behavior of Wolves specifically for you for only $16.05 $11/page Learn More However, they are much larger than the dogs. An adult male wolf grows larger than their female counterparts of the same age do. Most of the wolves are in Asia, North America, and Europe among other locations on the globe. The largest type of a wolf is the gray or timber wolf, which can live in any habitat from hot deserts to cool areas in the mountains. Just like dogs, wolves are social predators as depicted in the way they move and live like a family in groups known as packs. A pack is normally made up of not more than seven wolves, which largely depend on their number and the amount of food available for them. The animals carry out all their daily activities, which are mainly dominated by looking for food as a group. A couple who give birth to new members of the group heads each pack. ââ¬Å"Unlike many mammalian systems, whereby the dominant males have got many mates and the subordinate few or non, the dominant male wolves may only have only one mate while the subordinates have noneâ⬠(Harrington, Fred and Paul 221). After the young ones have grown up and can take care of themselves, they can move out of the pack to find their mates to start a new pack. Alpha is the name given to the dominant male leader of the pack. The dominant female is referred to as the alpha female. Hierarchy in the pack is observed as members of the pack show respect to the dominant or the superior ones. They do that through exhibiting submissiveness by the use of body postures and facial expressions. There is a limitation in the breeding proc ess because only the dominant partners can breed. In order to survive, a wolf must strive to achieve three things in life, which include a mate, food resources, and an area or territory. It can do this by killing an established breeder. However, in doing this, the wolf puts itself at the risk of being killed by its fellow wolves. The other option it can take is joining a pack, luring out a mate, and dispersing to an area that is not occupied (Mech and Luigi 25).Advertising Looking for term paper on biology? Let's see if we can help you! Get your first paper with 15% OFF Learn More It takes approximately a period of two months after conception for a female to give birth. A female wolf can give birth to between four to seven pups. The pups are all born blind and it takes them about a year to reach physical maturity. Summer time is a very important period for the breeding of the wolves. ââ¬Å"During the three to four months after parturition, the pups must be a dequately fed to ensure that their physical development is sufficient to survive the rigors of the late fall and winterâ⬠(Harrington, Fred and Paul 81). Nevertheless, the pups do not become sexually mature until they are two years old. Naturalistic Observation of the wolves While human beings make use of physical borders to mark their territories, some territorial mammals make use of scent marking to distinguish the boundaries of the places where they live. Some animals like dogs and wolves scent mark mainly through urination and defecation, while others like the cats rub their body parts against surfaces. This way, animals are able to pass a certain message from one animal to another (Alcock 51). All animals apart from human beings lack the ability to talk in order to pass messages from one to the other. As for animals, they have different forms of communication. By keenly observing the way they behave, one can easily tell that all animals do communicate with one another. The y make use of facial expressions, sounds, and body language to pass different kinds of information. The sounds made by certain animals are different from those made by others, depending on the kind of message that is being passed (Alcock 53). All these also apply to the wolves whose inferior members show submissiveness to the superior ones by encircling them with their noses raised up. Just like dogs do on sensing danger, wolves also erect their ears in times of danger and in addition to that, they open their mouths wide. Just like the other carnivores, the wolves have strong muscles. They also have a strong sense of sense of smell and sight. ââ¬ËThe sense of smell is probably the most acute of the wolfââ¬â¢s senses. Unlike human beings, wolves are strongly reliant on odors to acquire information about food or danger, as well as, all that concerns the outside world (Mech and Luigi 80). That way, they are able to kill animals, which are larger than they are in terms of size. To make getting food easier, they prey on the sick and weak animals and in addition to that, they eat very fast to avoid being robbed off their catch. The wolves normally target the deer, moose, the beavers, and the elk as their prey (Harrington, Fred, and Paul 35).Advertising We will write a custom term paper sample on The Natural Behavior of Wolves specifically for you for only $16.05 $11/page Learn More In case an enemy tries to steal their food, it will only be lucky to get the poor quality parts of the meat. This is because the wolves are very clever to feed on the best parts first once they get hold of their prey. In addition to their diet, the wolves feed on birds, berries, fish, worms, mice, and insects especially when they are not able to catch the large preys. There are rumors that wolves also eat people but it has not yet been proved true. The unique scent marking behavior of wolves Wolves are territorial by nature because they use their scents to mark their own territorial boundaries. It is the duty of leaders of the pack to urinate near the ends of their territories to mark them. ââ¬Å"Wolf scent marking behavior used for territorial advertisement includes raised leg urination (RLU) and perhaps standing urination (STU) by males, flexed leg urination (FLU) and possibly squat urination (SQU) by female and perhaps defecation (SCT) and ground scratching (SCR)â⬠(Mech and Luigi 25). The scent markings are said to reduce as one gets inside the territory. During patrols by the wolves in their territory, the number of scent markings is normally very high. The size of their territories depends on the nature of the habitat and the type of breed. It has been a little bit hard for researchers to track them down for study because of their frequent movements and their few numbers. There is a diminished wolf habitat and population because of the increasing human population and urbanization. The wolvesââ¬â¢ natural habitat continu es to suffer from extinction as human beings use the habitants for settlement and other activities (Harrington, Fred, and Paul 120). The wolves spent most of their time at the core; a place that is approximately at the centre of the territory. For safety purposes, the places where the pregnant females give birth are always near the core. If the wolves loose all their off springs, they continue to live in the territory. Even when one of the breeding pair dies, the other one remains there until another mate comes (Mech and Luigi 28). The non-breeding members of the pack offer the protection to the breeding mother and the pups. When there is danger, wolves normally howl and bark to pass the message to the rest of the members of the pack. That does not mean that, they all gather there, they spread out in the vast territory only reassembling when the supply of food is scarce in order to fight for it.Advertising Looking for term paper on biology? Let's see if we can help you! Get your first paper with 15% OFF Learn More Any wolf that does not belong to a certain pack is able to know the territories that have been occupied. This is because, by urinating near the edges of their territories, the wolves leave behind scent marks. They do it with one leg high up and that is followed by scratching the ground (Mech and Luigi 25). Additionally, it also enables them to know the presence of their prey and enemies, after which, they prepare themselves to deal with the situation at hand. The sad thing about their fascinating this natural behavior of wolves is the fact that it accounts for more than ninety percent of the lives lost by the wolves. Just as human beings behave when their territories are interfered with, the wolves fight for what belongs to them. Of course, the pack with the strongest or the largest number of wolves gets to win the fight leaving the members of the weak pack dead. ââ¬Å"Wolves do fight to death in the wild and the losers are usually wolves encountered on a territory edge or inside a neighborââ¬â¢s territoryâ⬠(Harrington, Fred and Paul 5). A predator is more likely to kill one of the wolves if they are in a pack than when each is alone. Cases of deaths arising because of attacks by predators occur mainly when the animals are together. Implications of the Naturalistic Observation The observation made on the scent marking behavior of wolves indicates that it is one of their forms of communication. If they are able to sense the entry of an enemy into their pack and prevent other wolves from entering into their territory, then it only means one thing. They are able to pass a certain message by leaving scent marks through urinating at or near the edges of their territories. Once a foreign wolf senses the scent marks, it is able to understand that that particular territory is occupied by another pack. That way, a message has been passed, and the wolf does not interfere since it is aware of the consequences that could result because of crossing boundaries. Li mitations of the Research It has been difficult for researchers to do a thorough study of the natural behavior of wolves because of their low population and frequent movement (Harrington, Fred, and Paul 120). On the other hand, the scientific explanation behind the unique scent in the urine has not yet been established. Finally, it is not known if other animals, which are not wolves have the ability to recognize the scent of the wolvesââ¬â¢ urine. Future Directions of the Research Researchers have been able to bring to the peopleââ¬â¢s understanding the scent marking behavior of wolves. The scientific explanation behind this unique behavior has not yet been ascertained. Therefore, researchers should go further in research to determine the chemical components present in the animalââ¬â¢s urine, which enables them to scent mark. In addition to that, they should also do thorough research to determine whether other animals apart from the wolves can be able to detect the scent. C onclusion From the above discussion, it is clear that almost all animals have their diversified ways of communicating with each other given the fact that they cannot express themselves through speech, as human beings do. As for the wolves, they communicate via scent marking. Scent marking is therefore, the unique way through which, wolves pass information to each other, especially with regard to marking their boundaries. This characteristic behavior is of great significance to the wolves because it enables them to survive, in other words, it is a survival tactic ((Harrington, Fred, and Paul). This is because the wolves are able to mark their territories and protect their prey from external predators. They are also able to note the entry of enemies and thus they can prepare to deal with them. Alcock, John. Animal Behavior: An Evolutionary Approach. Sunderland, Mass: Sinauer Associates, 2009. Print. Harrington, Fred H, and Paul C. Paquet. Wolves of the World: Perspectives of Behavior , Ecology, and Conservation. Park Ridge, N. J: Noyes Publications, 1979. Print. Mech, L D, and Luigi Boitani. Wolves: Behavior, Ecology, and Conservation. Chicago [u.a.: Univ. of Chicago Press, 2003. Print.
Monday, October 21, 2019
Plumber and Related Words
Plumber and Related Words Plumber and Related Words Plumber and Related Words By Maeve Maddox This post was triggered by the misspelling of the word plumber in the following passage: Your plummer can be as creative or more than your favorite rock star or painterâ⬠¦ What happens in his head when he needs to find a way to solve your unique sink problem is the same process that takes place in a musicians headâ⬠¦ The b in plumber derives from the fact that, until fairly recently, water pipes were manufactured of lead. The symbol for lead in the Periodic Table of Elements is Pb. The symbol derives from the Latin word for lead: plumbum. Around 1100, a plumber was a worker in any sort of lead. In the 19th century the word acquired the meaning workman who installs pipes and fittings. The Nixon administration, concerned about information leaks, created a special investigative unit called the Plumbers. A plumb line (also called a plumb-bob or a plummet) is a piece of lead hung on a string. Builders use plumb lines to gauge a vertical line. As a verb, plumb has various meanings. To plumb the depths is to measure the depth of water by dropping a weighted line of a known length. Figuratively it means to experience something deeply. The writer plumbed the depths of despair. To plumb a chimney or other object under construction means to adjust or test it to be sure its straight. Three other words that derive from the Latin word for lead are plummet, plunge, and aplomb. Besides being a synonym for a plumb line, plummet can be used as a verb. One sense is to fathom, to take soundings. Its more common use is with the meaning to fall rapidly. Plummet is a good word to describe a precipitate and heavy fall. Florida tomato prices plummet, consumers win Daily stress and worry plummet after age 50 A fireman and a policeman held the ends of a horse blanket to try to catch the next falling girl, but the blanket split in half as the body plummeted right through and hit the pavement. The verb plunge comes from Vulgar Latin plumbicare, to heave the lead. Like plummet, the word suggests a heavy weight falling in a straight direction or forceful movement into something or in a downward direction, often into water. The expression to take the plunge means to commit oneself. The fashion term plunging neckline is documented from 1949. So saying, Nigel, with the light, of adventure gleaming in his joyous eyes, drew his sword and plunged swiftly into the forest. In one of the most dizzying half-hours in stock market history, the Dow plunged nearly 1,000 points Dome plunged deep into sea to cap U.S. oil leak The noun aplomb means confidence. The connection to the lead/plumb line idea is that a confident, assured person stands up straight. By September 10, 2001, Rudolph Giuliani seemed to have worn out his welcome as Mayor of New York, but the sorrier aspects of his two terms of office were all but wiped from collective memory by his aplomb amidst the chaos of 9/11. He [Ellis R. Dungan] transcended barriers with aplomb Want to improve your English in five minutes a day? Get a subscription and start receiving our writing tips and exercises daily! Keep learning! Browse the Vocabulary category, check our popular posts, or choose a related post below:Fly, Flew, (has) FlownFlied?Capitalization Rules for the Names of GamesThe "Pied" in The Pied Piper
Sunday, October 20, 2019
Microsoft to improve buying experience at retail. (Thats shopping to you and me.) - Emphasis
Microsoft to improve buying experience at retail. (Thats shopping to you and me.) Microsoft to improve buying experience at retail. (Thats shopping to you and me.) Microsoft has announced its to open its own shops, in a clear bid to grab a slice of the Apple retail action. Apple trades on its image as the quintessence of cool: all innovative design and sleek lines. Microsoft may face an uphill battle in this respect, at least if its press release announcing the move is anything to go by. It quotes Kevin Turner, Microsofts chief operating officer, as saying: Were working hard to transform the PC and Microsoft buying experience at retail by improving the articulation and demonstration of the Microsoft innovation and value proposition so that its clear, simple and straightforward for consumers everywhere. What? you may ask. Good question. I was going to offer a translation, but Im afraid its stumped me. Some clear, simple and straightforward language might be a good start, Mr Turner.
Saturday, October 19, 2019
Dominant Masculinity over Fragile Femininity in Pornography Essay
Dominant Masculinity over Fragile Femininity in Pornography - Essay Example The book Getting Off: Pornography and the End of Masculinity by Robert Jensen show predominant humiliation of women through pornography and its mass production.First and foremost, one should agree with Jensen in his argument on the end of masculinity through constant mortification of the female honor. The author is straight-forward in what pornography symbolizes for everybody. It is a mirrored look of how men see women (Jensen 122). In fact, the author gives lots of examples coincided with his personal stories so as to make the whole thing really personal for each reader. The use of gang-bangs and other porn scenes where male dominance is obvious characterizes pornography as a means to make men senseless toward women and become more aggressive instead.Notably, Jensen speaks on the issue of female fragility in a sad tone. In this respect, many episodes from his book reflect on why women are so easy to be subject to menââ¬â¢s obscenity and aggression. Jensen gives his way of reasoni ng on this issue, namely: ââ¬Å"It hurts to know that no matter who you are as a woman, you can be reduced to a thing to be penetrated and that men will buy movies about thatâ⬠(Jensen 14)â⬠¦ This is a so-called interpretation that a womanââ¬â¢s body has become valuable solely due to its option of being penetrated by means of violent fellatio, double or triple penetrations, etc. Once again, the male dominance goes without saying in this context.It is about time to think of current generations of boys. Porn movies impose a huge desire to be aggressive and senseless toward girls on them so that to call those girls just whores as a result. Needless to say, all porn movies are normally misogynistic. The role of a man is not that important to the audience of viewers, but the way in which a woman oohing and aahing having male genitals in different parts of her body. Thus, the youngest layers of the society inherit the need for being rude and first-class (boys) and the need to comply with such attitudes (girls). As a matter of fact, such behaviors are already included in the social construct. It is a complete model of men-women interaction at every stage of their communication up to some intimate moments, so to speak.
Friday, October 18, 2019
What are the effects of chemicals on children Essay
What are the effects of chemicals on children - Essay Example the most dangerous elements scientists distinguish ââ¬Å"air pollutants, pesticides and persistent organic pollutants (POPs), lead, mercury, arsenic, mycotoxins and hazardous chemicals in the workplaceâ⬠(Chemical Safety). This study aims to search for the effect of chemicals on children`s health and wellbeing and possible measures of harmful effect prevention. Children may get access to chemicals indoor and outdoor through water, soil, house dust, nourishment and shopper items, in the environment where they dwell, study and play. Since specific chemicals can cross the placenta, they can also be transferred to children during pregnancy. Feeding newborn children with breast milk can also expose children to potentially harmful chemicals. As a rule, nobody realizes to the full extent what chemicals may do harm to individuals, particularly infants and babies who are prone to bite things or rub them on the skin. For a significant number of these mixes, there has been almost no examination to explore kids presentation to them. However, some scientists stress over potential dangers in light of the fact that it is presently clear that many chemicals untested for potential wellbeing impacts are found in ordinary things, for example, clothes, footwear, furniture, and toys. Kids are exceptionally defenseless taking into account their hand-to-mouth pr actices, floor play and developing immune ad nervous systems. Producers claim that there is no any threat considering the substances in an item, and it does not mean that any requirements of manufacture were violated. If some chemical from the list of harmful substances is detected in the item on the Washington state rundown is found in a toy or diversion, it does not consequently mean there are grounds for concern as people cannot have contact with these substances at all (Kay, 2013). Erry et al. explore the influence of PVC on children`s organism, which turned out to be extremely negative. In the research, a number of items
Presidential Powers Essay Example | Topics and Well Written Essays - 1250 words
Presidential Powers - Essay Example Under the devolved system of governance, the Presidentââ¬â¢s powers were trimmed and redistributed to the local governments. However, the president still enjoys three sources of power that include constitutional, institutional, and political sources. This present essay will focus on these current sources of power for the presidency and it will begin with an assessment of the constitutional powers of the President, followed by an assessment of how the 20th century presidents of the U.S have been able to use institutional and political resources to overcome challenges brought about by weak constitutional presidential powers. Lastly, the essay will highlight on the likely future balance of power between the Presidents and the Congress. Constitutional powers of the President It is correct to argue that the ratification of the constitution resulted in the presidency having weak powers. According to Ginsberg et al., these constitutional powers of the President are spelt out in Article T wo of the U.S constitution, which formally creates the executive arm of the central government that is made up of the President, the Vice President, and other presidential appointees. In particular, presidential powers are stated under section 2 of Article Two and they are split into three clauses (387-391). Clause 1 under Article Two gives the President exclusive powers over the U.Sââ¬â¢ armed forces since the President is the Commander-in-chief. Furthermore, the clause states that the President shall become the Commander in Chief of militia of several states when he/ she is called into service. However, according to Ginsberg et al., this is power is weakened by the fact that it is only Congress, which can declare war (375). Nevertheless, this fact has been an issue of contention, more so during the Bush era, when President George Bush circumvented the Congress and seemingly declared war on Afghanistan while the Congress simply approved his decision. With reference to the writin gs by Ginsberg et al., it can be argued that Clause 1 is vague in the sense that during times of war there is usually no time to debate and wait for the Congress to declare war (403-405). Therefore, it can be assumed that the President is acting in the best interest of the Nation by declaring war at a strategic time. Under Clause 2, the President has powers to make treaties and nominate Judges of the Supreme Court, public Ministers, Ambassadors, and key Officers of the U.S. However, this power is watered down by the fact that the President must first seek the advice and consent from the senate before making any Treaty and nominations and there are instances where the senate has repealed certain treaties signed by Presidents (Ginsberg et al. 412-415). The third Presidential power is spelt out under Clause 3, which gives the President Powers to make a recess appointment that expires when the next session of the senate ends or until the appointee is confirmed by the senate. This Presid ential power is also weakened by the fact that these appointments are not permanent and they are only made when the senate is on recess. How U.S Presidents in the 20th century have used institutional and political resources to overcome weakness of Presidential powers With references to the writings by Ginsberg et al., he noted that U.S Presidents in the 20th century as well as the 21st century have laid claim to certain inherent powers that they feel are intertwined with the powers that have been granted to them under Article Two of the constitution (Ginsberg et al. 423-428). Moreover, the Presidents have been able to lay claim on this inherent powers because the constitution is
Thursday, October 17, 2019
Maryland Research Paper Example | Topics and Well Written Essays - 250 words
Maryland - Research Paper Example ack Obama, in proclaiming the $4.35 billion Race to the Top activity a year ago, said the project is dependent upon a basic standard: "whether a state is primed to do what meets expectations." Maryland is prepared, as well as ready and equipped to proceed with the advancement that has been made. MSDE worked with our nearby school frameworks and a mixture of accomplices to assemble Marylands winning arrangement. We are resolved to proceed with our States energy since Race to the Top is an element of the federal governments American Recovery and Reinvestment Act Program. Marylands vision for change is to revise the Prek-12 Maryland State Curriculum, appraisals, and responsibility framework dependent upon the Common Core Standards to guarantee that all graduates are school and vocation prepared. It also has a vision to build a statewide innovation foundation that connections all information components with investigative and instructional instruments to screen and push understudy accomplishment. Another vision is to redesign the model for arrangement, advancement, maintenance, and assessment of instructors and principals. Finally, Maryland has a vision of fully actualizing the inventive Breakthrough Center methodology for changing low-performing schools and
The recruitment, selection and training methods of LVMH Essay - 1
The recruitment, selection and training methods of LVMH - Essay Example Given below is the systematically defined roadmap for underlying research in order to achieve objective of the research. 3.1 Purpose of Study Human resource management has growingly taken the strategic position in the business management and now organizations have realized the importance of managing human resource strategically. Since realization of fact that human resource is the most important capital asset all scale businesses have started to develop mechanism that ensure increased efficiency in business operations. Further, for developing such mechanism most of the businesses try to replicate mechanism employed at other businesses that have gained success across the board. Hence, the purpose of the research is to explore the human resource management of LVMHs that has gained success as an international organization. More specifically, the research explores the recruitment, selection and training section of the human resource management functions of LVMH. LVMH has 100,000 employed with 80% of the employees working for organization outside the country of origin, France. With such business model, the business has successfully managed the diverse employee base across various countries. Hence, exploring the mentioned functions of LVMH will fulfill the purpose of research of identifying the recruitment, selection and training procedure employed at LVMH. With assessment of the processes the research also fulfills the purpose of aligning information pertaining to the success of LVMH presented in financial statement as well as form K. The other purpose that has been fulfilled by the research in this study is the presentation of recruitment, selection and training procedure for the businesses that intend to replicate the human resource model of successful organization to respective organizations. In addition to the above purposes that would benefit businesses on practical aspects, the research is aimed to contribute to the academic literature the assessment of certai n human resource function of internationally successful organization. As stated the purpose of the above research is to explore information about the organization; hence, the understudy research is regarded to be exploratory research. 3.1.1 Research Question The research question is concisely presenting the objectives of the study. Defining research question the researcher develops postulates that are to be specifically addressed by the research (Patton, 1980). Since every domain of study has its own expansions; therefore, developing research question facilitates the researcher with defining scope of the research to be addressed. With these factors, the researcher in the research presents specified set of questions that study intends to explore. Hence, the research question that underlying research, entitled Recruitment, Selection and Training of LVMH, is aimed to address includes following: What methodologies are adopted at LVMS for developing the candidate base under recruitment? What are the selection techniques employed at LVMH for short listing and then selecting the candidate for the particular job? What training methodologies are employed at LVMH to align the new employees on the same frequency of other employees? It further aims to explore the training methodol
Wednesday, October 16, 2019
Maryland Research Paper Example | Topics and Well Written Essays - 250 words
Maryland - Research Paper Example ack Obama, in proclaiming the $4.35 billion Race to the Top activity a year ago, said the project is dependent upon a basic standard: "whether a state is primed to do what meets expectations." Maryland is prepared, as well as ready and equipped to proceed with the advancement that has been made. MSDE worked with our nearby school frameworks and a mixture of accomplices to assemble Marylands winning arrangement. We are resolved to proceed with our States energy since Race to the Top is an element of the federal governments American Recovery and Reinvestment Act Program. Marylands vision for change is to revise the Prek-12 Maryland State Curriculum, appraisals, and responsibility framework dependent upon the Common Core Standards to guarantee that all graduates are school and vocation prepared. It also has a vision to build a statewide innovation foundation that connections all information components with investigative and instructional instruments to screen and push understudy accomplishment. Another vision is to redesign the model for arrangement, advancement, maintenance, and assessment of instructors and principals. Finally, Maryland has a vision of fully actualizing the inventive Breakthrough Center methodology for changing low-performing schools and
Tuesday, October 15, 2019
Business Plan Essay Example | Topics and Well Written Essays - 4000 words
Business Plan - Essay Example ............................................page 4-5 5). BUSINESS AIMS..............................................................................................page 5 6). BUSINESS OBJECTIVES..............................................................................page 5-6 7). BUSINESS PRODUCTS AND SERVICE.......................................................page 6-7 8). MARKETING MIX............................................................................................page 7 9). BARRIERS TO ENTRY....................................................................................page 7-8 10). DEFINITION OF TARGET MARKET.........................................................page 8-9 11). BUSINESS ENVIRONMENT..........................................................................page 9-10 12). COMPETITOR ANALYSIS.............................................................................page 10-11 13). MARKETING PLAN.................................................... ....................................page 11-12 14). OPERATIONAL PLAN....................................................................................page 12-14 15). FINANCIAL PLANNING AND FORECASTS..............................................page 14-15 16). RISK MANAGEMENT.....................................................................................pag 15 17). HUMAN RESOURCE ISSUES........................................................................page 15-16 18). ... INTELLECTUAL PROPERTY MANAGEMENTâ⬠¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦page 20 22). CONCLUSIONâ⬠¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦...page 20-21 1). EXECUTIVE SUMMARY This business plan is designed to secure funding for my idea, which is basically a restaurant and cookery school in Leicester city and/or surrounding villages in the United Kingdom. It covers the following topics: the business idea, business vision, a mission statement, aims, objectives, the product or service, marketing mix, barriers to entry, a definition of target market, the business environment, competitor analysis, marketing plan, operational plan, financial planning and forecasts, risk management, human resource issues, design strategy, time management, potential five year development plan and intellectual property management. I am seeking money from pot ential investors, business advisors, and bank managers who will see this business plan. Therefore, in this business plan, the following key questions are addressed: 1). How much investment do I require?; 2). What percentage equity am I offering in return for the investment?; 3). How will the investors obtain a return on their investment?; 4). What is the potential financial exit strategy for the investors? The business plan provides the answer to all these relevant topics and questions. 2). THE BUSINESS IDEA The business idea of Extensively British restaurant and cookery school comes from its ownerââ¬â¢s dream. It will be a 100 seat restaurant with a 20 seat lounge, and 2 rooms for instruction with a capacity for 30 students yearly. Its specialization is British cuisine with an Italian touch. The students will take classes from the cookery school, so the restaurant and cooking courses will be in the same place. It
Monday, October 14, 2019
Mahindra project report Essay Example for Free
Mahindra project report Essay After concrete efforts of our Management, the students of Kohinoor Management School got this esteemed opportunity to have an Industrial visit to a prestigious company like Mahindra and Mahindra Ltd. We appreciate the efforts of the management of KMS MM for executing this successful Industrial trip. Introduction to Mahindra: Mahindra Mahindra Limited is the flagship company of the Mahindra Group, a multinational conglomerate based in Mumbai, India. The company was set up in 1945 in Ludhiana as Mahindra by brothers K. C. Mahindra and J.C. Mahindra. Mahindra Mahindra is a major automobile manufacturer of tractors, utility vehicles, passenger cars, pickups, commercial vehicles; its tractors are sold on six continents. It has acquired plants in China and the United Kingdom, and has three assembly plants in the USA. MM has a global presence and its products are exported to several countries. Its global subsidiariesà include Mahindra Europe Srl. based in Italy, Mahindra USA Inc., Mahindra South Africa and Mahindra (China) Tractor Co. Ltd. MM is one of the leading tractor brands in the world by volume. It is also the largest manufacturer of tractors in India with sustained market leadership of over 25 years. It designs, develops, manufactures, and markets tractors as well as farm implements. The Journey Beginsâ⬠¦. We reached the Mahindra plant at Kandivali, Mumbai. We headed to the Conference room and were briefed about the Company by a presentation on the leadership and the entire group of MM followed by the Q A Session which lasted for an hour. The honors were done none other than Mr. Shirish Tawde, the Deputy General Manager (DGM) of the Company. Accompanying him were Mr. Kishor Sonawane (Manger Business Excellence), Rajendra Sawant (Sr. Manager Business Excellence), Mr. Mahesh Dalvi (Manager Business Excellence, Sector Sustainability). With such dignitaries explaining us the world of MM, we were just as grateful. This plant mainly deals in manufacturing of Tractors and Farm Equipments. The plant is one of the oldest manufacturing plants in the production of tractors in India. After decades in leading the tractor sector MM have diversified into the roots of farming and have positioned themselves in the Farm Sector. After being briefed through the introduction of MM plant, we were about to explore the Indiaââ¬â¢s most Prestigious Companies. We were divided into 2 groups of 15 people so as to have individual attention . We visited 3 units of the plant right from examination of engine parts, assembling of engine and main manufacturing of tractors. They manufacture 2,00,000 tractors annually. The FES contributes 35% market share. Hands on approach to Production (where theory meets practical): Each Group was taken separately and explained functioning of the plant. A lot of theory is learnt is class regarding how the manufacturing units focus on Total Productivity, Total Quality, Zero Defect, etcâ⬠¦but by far this was theà first hands on experience on how does a Manufacturing unit or plant works. Here we are explained about how the assembly line manufacturing process works. This section of the plant deals with the installation of the main engine of the tractor. In this picture we are introduced to how the stations work in co-ordination to get optimum results. In the pictures below, the students are taken through a complete channel of stations on the assembly station and the supervisor explaining each of this complicated process. The lag or lead time is calculated and each one at every station tries to improve on it so as to reduce the time effect in assembling each engine. The units where tractors are manufactured in assembly lines follow Total Quality Management (TQM) and Total Productivity Management (TPM). Every sub-unit contributes to the production. They avoid material handling losses with pulleys and fork-lifts. All these techniques add value to the production. Indeed there is no surprise they improve their quality and reduce time with ever unit of production of tractor. Here, we are shown how the final tractors are put in place Students Opinion: Kohinoor Management School gave us the Golden Opportunity to visit the Mahindra and Mahindra plant at Kandivali. It was a great experience to know the organization internally. They are successful enough to balance between Business Excellence and Individual Dignity. Their main focus on farm tech prosperity is what like me a lot, as agriculture is the base of the Indian Economy. -Pratibha Shinde. Visit to the M M was an eye-opener. The journey unfolded various aspect of the tractor division. Starting from the nuts and bolts, the engine, to the massive structure which forms the backbone of the Indian farms and agricultural sector. The gains or the take away from the visit were splendid. The use of Japanese technology in the assembly line, the step by step process layout, the plan B; the vision of always staying ahead were the insights. Lots of management mantras were demonstrated and inculcated. A great learning and an honour to see the invasion of the GREAT INDIAN TRACTOR DIVISION. -Yogendra Joshi. It was my first Industrial visit to any manufacturing plant and enjoyed every bit of it. To be a part of such an esteemed organization and having a look through all their process was an intriguing experience after all. -Shraddha Salunke On behalf of all the Management and the students we take this opportunity to thank the entire team of Mahindra and Mahindra for providing us with the practical information and well as wonderful hospitality. We take moment to offer our greetings to the entire Mahindra and Mahindra team.
Sunday, October 13, 2019
Carbon Mesoporous Material Hybrid Catalyst
Carbon Mesoporous Material Hybrid Catalyst Facile and clean transformation for synthesizing secondary arylamines through one-pot reductive amination of aniline, using aldehyde catalyzed by the supported nickel and poly(vinyl sulfonic acid) on mesoporous carbon CMK-3 (Ni/PVSA/CMK-3) as a novel acid-metal bi-functional heterogeneous catalyst. Sodium borohydride was used as the source of hydrogen for the reduction of imine. The reaction was performed at room temperature, in a short reaction time, without any by-products. Various characterization techniques including FT-IR, XRD, TG, BET, SEM, TEM, DRS-UV and AAS were employed to reveal the relationship between catalyst nature and catalytic performance. Reaction results demonstrate that the optimized Ni/PVSA/CMK-3 catalyst shows comparable catalytic performance thanks to the nickel metals and the acidic nature of polymer in mesopore channels of CMK-3. This method has several advantages such as, eco-friendly (used water as solvent), moderate to high yields, simple work-up procedure and catalyst filtered easily and reused without obvious loss of activity. 1. Introduction Nowadays, amines are privileged in industry that have found prevalent applications as intermediates for pharmaceuticals, biologically active compounds, rubber, solvents, fine chemicals, dyes, herbicides, and in the manufacture of detergents and plastics. Reductive amination demonstrate one of the most versatile and convenient methods of amine synthesis. This reaction has two steps including formation of an imine during reaction between primary amine and a carbonyl substrate, and reduction of the imine with adequate hydride source. There are two detached approaches for the reductive amination: the direct approach, which uses the in situ-generated imine, and the indirect approach, which uses the prior isolated imine. The former approach has several advantages such as one-pot procedure, increasing yields, having simple setup, easily separated from the product, being stable and compatible reagents, and the mild reaction conditions. To this end, over the past decades, researchers have been reported several studies on reductive amination reaction with several different catalysts, which among them, heterogeneous catalysis are prominent than homogenous catalysis owing to separate and recover capabilities. Moreover, it has been proven that accomplish this reaction needs two character including metallic and acidic; consequently, bi-functional heterogeneous catalysts are useful in this reaction. Recently, several metal nanoparticles acted as a hydride transfer such as Pt, Ni, Cu, and Pd. Despite of the fact that an effective control of particle size and a uniform distribution of nanoparticles in catalytic applications are generally predicted, nanoparticles typically accumulate together in bulk-like materials that hardly reduce selectivity and the activity of catalysts. To overcome with this problem, mesoporous silica, zeolites, polymers or macromolecular organic ligands have been used in order to immobilize metal nanoparticles in their pores. Mesoporous silica materials and zeolites have excellent order and surface area than other materials like polymer and etc.; subsequently, they are sufficient for catalysis approaches. Lately, mesoporous silica used for producing mesoporous carbon (CMK-n) as hard template. These materials contain several benefits compared to mesoporous silica and zeolites for instance, high mechanical stability, high thermal stability in nitrogen atmosphere, superb stability in strong acids and bases, and other engrossing properties such as narrow pore size distributions, high surface areas, and ordered frameworks. In addition, mesoporous carbon materials have hydrophobic nature on their surfaces and it helps to embed nanopolymers in their pores. In our previous studies, it asserts that when polymer embedded into mesoporous materials, they have perfect function. Owing to the fact that they have small particles and subsequently having high surface areas. Moreover, polymer nanoparticles fix in porous and they could not leach from their supporters. Accordingly, in this work, we will introduce a novel heterogeneous organic hybrid catalyst based on a carbon mesoporous material. In this circumstance, mesoporous carbon CMK-3 replicating from mesoporous silica SBA-15 was prepared and used as suitable support for Nickel nanoparticle/poly vinyl sulfonic acid/CMK-3 (Ni/PVSA/CMK-3). Furthermore, the catalyst was used effectively for the one-pot reductive amination of amine compounds using aldehyde in the presence of a small amount of NaBH4 as a mild reducing agent and two sort of solvent containing water and acetonitrile at room temperature without any by-products. 2. Experimental method 2.1. Catalyst characterization The samples have been analyzed by FT-IR spectroscopy (using a PerkinElmer 65 in KBr matrix in the range of 4000-400 cm-1). The thermal gravimetric analysis (TGA) data were obtained by a Setaram Labsys TG (STA) in a temperature range of 30-650 -C and heating rate 10 -C min-1 in nitrogen atmosphere. The X-ray powder diffraction (XRD) of the catalyst was carried out on a Bruker D8Advance X-ray diffractometer using nickel filtered Cu Kà ± radiation at 40 kV and 20 mA. The BET specific surface areas and BJH pore size distribution of the samples were determined by adsorption-desorption of nitrogen at liquid nitrogen temperature, using a Series BEL SORP 18. For the measurement of nickel, a Perkin Elmer AAnalyst 300 atomic absorption spectrophotometer was used. The slit width, linear range and wave length for Ni were 0.2 nm, 2 and ppm232 nm, respectively. Scanning electron microscope (SEM) studies were performed on Philips, XL30, SE detector. Transmission electron microscope (TEM) observati ons were performed on a JEOL JEM.2011 electron microscope at an accelerating voltage of 200.00 kV using EX24093JGT detector in order to obtain information on the size of nickel nanoparticles and the DRS UV-vis spectra were recorded with JASCO spectrometer, V-670 from 190 to 2700 nm. Moreover, X-ray photoelectron spectra (XPS) was recorded on ESCA SSX-100 (Shimadzu) using a non-monochromatized Mg Kà ± X-ray as the excitation source. The products were characterized by 1H NMR and 13C NMR spectra (Bruker DRX-500 Avance spectrometer at 500.13 and 125.47 MHz, respectively). Melting points were measured on an Electrothermal 9100 apparatus and they were uncorrected. All the products were known compounds and they were characterized by FT-IR, 1H NMR and 13C NMR. All melting points are compared satisfactorily with those reported in the literature. 2.2. Catalyst preparation The employed mesoporous carbon (CMK-3) was synthesized following the method reported by Ryoo using SBA-15 as template. 2.2.1. Preparation of SBA-15 Mesoporous silica SBA-15 was prepared using block copolymer Pluronic P123 (EO20PO70EO20) template as a structure directing agent and tetraethylorthosilicate (TEOS) as the silica precursor through the addition of H3PO4 by novel method as described in the literature. In a general synthesis, Pluronic P123 (2 g) was dissolved at room temperature in deionized water (75.4 mL) and H3PO4 (4.2 mL, 85%), after that TEOS (4.6 mL) was added to the solution and synthesis was fulfilled by stirring at 35 -C for 24 h in sealed Teflon breakers, and it was consequently placed at 100 -C for 24 h. Afterwards, the solution was filtered, washed with deionized water, and lastly dried at 95 -C for 12 h in air. Template removal was accomplished by calcination in air using two successive steps; first heating at 250 -C for 3 h and then at 550 -C for 4 h. 2.2.2. Preparation of CMK-3 Mesoporous carbon CMK-3 was prepared using mesoporous silica SBA-15 as template and sucrose as the carbon precursor. 1.0 g SBA-15 was added to 5 mL aqueous solution containing 1.25 g (3.65 mmol) sucrose and 0.14 g (1.42 mmol) of H2SO4 (98%). The resulting mixture was heated in an oven at 100 -C for 6 h and next 160 -C for another 6 h. In order to obtain entirely polymerized sucrose inside the pores of the SBA-15 template, 5 mL aqueous solution containing 0.8 g (2.33 mmol) sucrose and 0.09 g (0.917 mmol) of H2SO4 were added again, and the mixture was subjected to the thermal treatment described above one more time. Then, it was carbonized under nitrogen gas flow at 900 -C for 6 h with a heating rate of 5 -C min-1. Finally, the resulting solid was washed with 1 M NaOH solution (50 vol. % ethanol-50 vol. % H2O) twice to remove the silica template, filtered, washed with ethanol until pH = 7, and dried at 100 -C for 4 h. 2.2.3. Preparation of Poly(vinyl sulfonic acid)/CMK-3 2.2.4. Preparation of Ni nanoparticle-poly(vinyl sulfonic acid)/CMK-3 At first, Vinylsulfonic acid sodium was converted into its acidic form using the ion exchange resin (Amberjet 1200 H, 2 equiv. L-1, Aldrich). Ni/PVSA/CMK-3 was synthesized as follows: in the first place, 1 mL aqueous solution of NiCl2.6H2O (0.5 M) was added to the obtained PVSA/CMK-3 (0.1 g) together with 3 mL of H2O. The mixture was heated for 5 h at 353 K. Next, the solution of NaBH4 [0.057 g (1.5 mmol)] dissolved in 5 mL methanol was added to the mixture drop by drop in 20-30 min. Then, the solution was stirred for 3 h. After that, adding the same amount of NaBH4 was repeated and again the mixture was stirred for 3 h. Consequently, the solution was filtered and washed sequentially with deionized water and methanol to remove excess NaBH4 and NiCl2, and was dried in room temperature to yield Ni/PVSA/CMK-3. The Ni content of the catalyst was estimated by decomposing. Known amount of the catalyst by perchloric acid, nitric acid, fluoric acid, hydrochloric acid, and the Ni content was estimated by atomic absorption spectrometer. The Ni content of Ni/PVSA/CMK-3 estimated by atomic absorption spectrometer was 2.1 mmol gâËâ1. 2.3. General procedure for one-pot reductive amination of aldehydes. A mixture of Aniline (2 mmol) and benzaldehyde (2 mmol) in water or acetonitrile (3 mL) was placed in a round bottom flask and stirred for 1 min at room temperature. Afterward, to the resulting mixture, Ni/PVSA/CMK-3 (0.04 g) and NaBH4 (6 mmol) were added and the mixture was stirred at room temperature until TLC showed the complete disappearance of the benzaldehyde. Then, the reaction mixture was quenched with water (10 mL) and the product was extracted with diethylether (2 10 mL). After they finished, the organic phase was dried over anhydrous Na2SO4, filtered and concentrated. In the end, the products were obtained very pure just by extract with diethylether in the majority of the reactions. The product was identified with a melting point, FT-IR spectroscopy techniques, 1HNMR and 13CNMR. 3. Results and discussion 3.1. Catalyst characterization Figure 1 shows the FTIR spectra of CMK-3 (a), PVSA/CMK-3 (b) and Ni/PVSA/CMK-3 (c). A broad band at around 3380-3470 cmâËâ1 was observed in all samples. The O-H stretching vibration of the adsorbed water molecules mainly caused it. Moreover, in the CMK-3 spectrum, there are not any signals belong to organic bonds, resulting from the complete carbonization of sucrose (Fig. 1a). The presence of a new absorption bands at 1041 and 1186 cm-1 attributed to the S=O group of PVS, affirming the existence of the grafted PVSA chains on the CMk-3. In addition, the band at about 1650 cm-1 is attributed to adsorbed water, which is similar to related reports[]. The presence of peaks at around 2940 cmâËâ1 and 1450 cmâËâ1 correspond to the aliphatic C-H stretching and bending in PVSA/CMK-3, respectively (Fig. 2b). The appearance of the above bands shows that PVSA has been attached into mesoporous of CMK-3 and the synthesis of PVSA/CMK-3 has been successful. The profiles of thermogravimetric analysis of PVSA/CMK-3 and Ni/PVSA/CMK-3 under nitrogen atmosphere are shown in Fig. 2. The degradation of Poly(vinyl-sulfonic acid) commences at 150C and this stage continues to a little less than 300C. The next stage involves only a little degradation and occurs over the temperature range of 300 to 500C. These evidence are shown Poly(vinyl-sulfonic acid) cannot tolerant the temperature due to polymers are not protect by any supporter. The TGA curves of PVSA/CMK-3 shows a small mass loss (around 5%, w/w) in the temperature range of 100-330 -C, which is apparently associated with degradation of SO2 and ethylene from PVSA (Fig. 2). At temperatures above 330 -C, PVSA shows one main stage of degradation. The mass loss for PVSA in the second step is equal to 11.5% (w/w) which correspond to the degradation of the methane. In light of the difference between the PVSA and PVSA/CMK-3 curves, it is clear that PVSA/CMK-3 has higher thermal stability and slower degradation rate than PVSAP. Hence, after hybridization, the thermal stability is enhanced significantly that is beneficial for the catalyst application. In addition, Ni/PVSA/CMK-3 shows two separate weight loss steps that are almost similar to the PVSA/CMK-3. The only difference is temperature between 330 and 445 C, which Ni/PVSA/CMK-3 shows slower degradation rate than PVSA/CMK-3 in these range. It asserts that the hybrid Ni/PVSA/CMK-3 had higher thermal stability than PVSA/CMK-3. It may be related to the presence of Nickel nanoparticles in the composite structure. Consequently, it is proper thermal stability is boosted after hybridization because of intense the catalyst application. Figure 1 shows the powder XRD patterns of SBA-15, CMK-3, PVSA/CMK-3 and Ni/PVSA/CMK-3. The low angle diffraction pattern of SBA-15 shows three reflections at 2à à ´ values from 0.5 to 2à ° including one strong peak at (100) and two weak peaks at (110) and (200), which corresponds to the well-known ordered arrangement of SBA-15 in the space group p6mm of 2-D hexagonal symmetry. The silica SBA-15 used as template to synthesis CMK-3. As can be seen, the XRD pattern of CMK-3 show three diffraction peaks at 2à à ´ = 1.04à °, 1.79à ° and 2.05à ° (Fig. 3b). It could be marked to (100), (110) and (200) diffractions of the 2D hexagonal space group p6mm, which is compatible with previous articles. After polymerization by poly (vinyl sulfonic acid), the X-ray diffraction of PVSA/CMK-3 shows the same pattern with CMK-3. This evidence indicates that the structure of the CMK-3 was retained after the polymerization (Fig. 3c). Albeit, the intensity of the characteristic reflection peaks of the PVSA/CMK-3 is found to be diminished (Fig. 1b). Composite contains less CMK-3 due to the dilution of the carbon material by PVSA; subsequently, this dilution can be responsible for a decrease in the peak intensity. By the way, the XRD patterns of CMK-3 and PVSA/CMK-3 are almost similar to SBA-15, which it shows CMK-3 is a accurate replica of the mesoporous silica SBA-15 and the polymerization process does not damage the structure of CMK-3. After immobilize nickel in the PVSA/CMK-3, Ni peak cannot be seen in XRD since the homogeneity of Ni particles in the Ni/PVSA/CMK-3, and it lonely shows an amorphous pattern at 2à ¸ values of about 44Ãâ¹Ã
¡ (Fig. 3, inside). In order to demonstrate the e xistence of Ni nanoparticles in the Ni/PVSA/CMK-3 catalyst was exposed to temperature (400Ãâ¹Ã
¡C). Meanwhile, amorphous Ni changed to crystalline and appear a peak with low intensity at 2à ¸ = 44.29Ãâ¹Ã
¡, which can be attributed to the small size of nickel nanoparticles and the plane (111) of fcc nickel. Eventually, after immobilize the nickel nanoparticles on composite, structure has not changed and it is represented a successful synthesis of the catalyst. The specific surface area, pore volume and the pore size of the CMK-3, PVSA/CMK-3 and Ni/PVSA/CMK-3 samples are summarized in Table 1. All samples exhibit a type IV adsorption isotherm with an H1 hysteresis loop by capillary condensation at relative pressure around 0.3-0.7 (Fig. 4). It is clear in table 1 that the PVSA/CMK-3 and Ni/PVSA/CMK-3 exhibits a smaller specific surface area, and pore volume in comparison to those of pure CMK-3. Thanks to the successful incorporation of the poly(vinyl sulfonic acid) into the mesoporous carbon. As can be seen, pore diameter increases in the PVSA/CMK-3 and Ni/PVSA/CMK-3 in comparison to CMK-3. This evidence shows the incorporation and growth of hyperbranched polymers and consequently produces the pressure (physical pressure on the wall of the channels) inside the CMK-3 mesoporous. By adding Ni nanoparticles into the PVSA/CMK-3, the specific surface area and pore volume decrease, asserting that nickel nanoparticles are located inside the pores o f the CMK-3. In spite of the fact that there are significant decreases in the pore volume and surface area, the pores of Ni/PVSA/CMK-3 were not blocked by deposition of the hyperbranched homopolymer and nickel nanoparticles. Moreover, the BJH pore size distribution curves of the PVSA/CMK-3 and Ni/PVSA/CMK-3 are exhibited a narrow pore size distribution (Fig. 5). It clarifies that the homopolymer and nickel nanoparticles are satisfactory distributed on the channels of the Ni/PVSA/CMK-3. This result is agreement with TEM analysis and shows the effective role of the hyperbranched polymer to entrap and uniformly disperse nickel nanoparticles. , , Fig. 6 gave the scanning electron microscopy (SEM) photographs of CMK-3 and PVSA/CMK-3 and Ni/PVSA/CMK-3. All the SEM images are shown rod-like morphology, which is attributed to carbon mesoporous. Although, virtually no significant differences observe in surface morphology between CMK-3 and PVSA/CMK-3, it is obvious that after hybridization the surface of CMK-3 is become coarser; indicating the most of polymerization of PVSA occurred in the pores of CMK-3, which was also supported by the decrease in surface area and pore volume as shown in Table 1. In addition, by immobilizing Ni nanoparticles, several spherical beads are seen on the mesoporous carbon. However, most of them are incorporated inside the carbon mesoporous structure, which is not observable in the SEM images. It is necessary to mention that after loading nickel nanoparticles on the surface of CMK-3, the structure of the mesoporous carbon is remained. Moreover, XRD analysis and TEM images confirmed this claim. The PVSA/CMK-3 and Ni/PVSA/CMK-3 were inspected by means of TEM micrographs technique (Fig. 7). The ordered hexagonal p6mm mesostructure of PVSA/CMK-3 and Ni/PVSA/CMK- 3 can be seen, indicating after polymerization and incorporation of PVSA and Ni nanoparticles, the ordered structure of mesoporous carbon is retained. Additionally, the places with darker contrast could be assigned to the presence of Pd particles with different distribution (Fig. 7c-d). As can be seen, the small dark spots could be ascribed to nickel nanoparticles with Ã¢Ë ¼X nm average diameter, presumably located into the mesoporous channels. On the other hand, larger dark spots are shown in fig. 7 c-d, which are corresponded to Ni nanoparticles agglomerate on the external surface with average diameter of Ã¢Ë ¼5-10 nm. Fig. 8 shows the DRS-UV of PVSA/CMK-3 and Ni/PVSA/CMK-3. previous reports were proven that DRS-UV of the cationic nickel have only d-d transitions peaks including 3T1g(P)ââ 3A2g (F) (368 nm) and 3T1g (F)ââ 3A2g (F) (576 nm), which these two peak do not show in Ni/PVSA/CMK-3. Moreover, the DRS-UV of Ni/PVSA/CMK-3 shows feature bands around 205 nm and 330 nm, which are attributed to the presence of Ni nanoparticles in these samples. By comparing these data, it can be found that cationic nickels are converted to the nickel nanoparticles by reduction of NaBH4. 3.2. Catalytic activity Synthesized nanocomposite was characterized by different methods in the former section. This section is introduced the application of this bi-functional catalyst to the reductive amination reaction. During two decade, enormous investigation devoted to develop environmental friendly synthesis. Since, using water as a reaction medium in transition metal-catalyzed processes is one of the most essential goal of sustainable chemistry. Water is nontoxic solvent, readily available, an inexpensive, nontoxic solvent and non-inflammable. It provides privilege over organic solvents from an environmental and an economic aspect. Accordingly, the effect of several parameters on the one-pot tandem reductive amination of aldehydes with aniline over Ni/PVSA/CMK-3 as acid-metal bifunctional catalyst was perused in water at room temperature and the outcome are as follows: At the first monitoring of experiments, diverse amounts of NiCl2.6H2O were tested to identify the effect of nickel nanoparticles concentration on the reductive amination reaction. Hence, the amount of NiCl2.6H2O to prepare Ni/PVSA/CMK-3 was changed from 1 mmol/g to 15 mmol/g and then measured by the Atomic Absorption spectroscopy technique (AAS) which are shown in Table 2. It is clear that the activity of catalytic steadily improved by increasing NiCl2.6H2O form 1 mmol/g to 5 mmol/g. According to the catalytic reaction mechanism, nickel nanoparticle mediated electron transfer from BH4- ion to the imine intermediates (Scheme 1). Subsequently, the amounts of H- sites on the catalyst surface are grown by increasing nickel nanoparticles. Thus, larger amount of hydrides can be transferred to the imine groups through the catalyst. On the other hand, by further increasing the amount of NiCl2.6H2O (more than 5 mmol/g), the catalytic activity was diminished, which can be attributed to after a certain amount of nickel chloride increases, a larger amount of nanoparticles is loaded on the surface of the CMK-3 that may have caused the mesopore channels to narrow. In Fact, the nanoparticle size will increase by increasing the amount of NiCl2.6H2O. Therefore, in some places, the pore size will narrow and it is able to lessen the rate of reactants diffusion into the porous. In one word, lower performance of the catalyst produced with higher NiCl2.6H2O concentration will be anticipated. Despite of this fact, it does not mean the pores are throughout clogged. According to these results, the catalyst provided by 5 mmol/g NiCl2.6H2O presented the best catalytic activity. To identify the effect of NaBH4 amount (as a hydride donor) on the reductive amination the reaction was carried out using various amounts of NaBH4 in the presence of Ni/PVSA/CMK-3 as catalyst. As shown in Table 3, the yield was increased by increasing the amount of NaBH4 (until 6 mmol). The excess values did not have any effect on the reaction. Therefore, 6 mmol NaBH4 was the best value to perform reductive amination reaction. The influence of the solvent on catalytic activity was investigated in the reductive amination reaction using Ni-PVSA/CMK-3 catalyst and NaBH4 as hydride donor, at room temperature. The results are gathered in Table 4. Four vital factor acts to fulfil reductive amination reaction including dielectric constant, dipole moment, solubility in NaBH4, hydrophobic effect, protic and aprotic solvent effect. The results revealed that the reaction time in ethanol solvent is slow due to NaBH4 hardly solving in ethanol and the reaction rate is tardy. In addition, the reaction rate in water solvent is slow because although dielectric constant and solubility of water in NaBH4 is high, carbon mesoporous CMK-3 have hydrophobic nature. It causes substances and catalyst cannot have perfect interaction together. The hydrophobic nature of acetonitrile and oxolane are higher than other solvent that presented above; thus, these two solvent have more similarity to hydrophobic nature of CMK-3. Moreover, dipole moment of acetonitrile is higher than other solvent. Thanks to this feature, the reaction rate increase. Whereas the methanol solvent has mediate circumstance of dielectric constant, solubility in NaBH4, and hydrophobic effect aspect, the reaction time diminish. It is noteworthy to mention that the combination of all these factors together cause this process. Regarding these situation, water and acetonitrile were finally selected as the solvent for the reaction because of their environmental friendly and highly efficient, respectively; and all other optimization and reaction separately accomplished by these two solvent. The effect of the amount of catalyst was defined for reductive amination reaction (Table 5). Due to the fact, the catalyst synthesized is worthy, it is decided that the amount of catalyst optimize by decreasing down to the 0.04 g, nevertheless the reaction time were increased. However, reducing the amount of catalysts until 0.02 g was not sufficient. Since, the quantity of 0.04 g for both solvent was found to be the best weight of catalyst. The reusability of the catalyst was studied by using Ni/PVSA/CMK-3 in water and acetonitrile solvent (Chart 1). After each cycle, the catalyst was filtered off, washed with water (10 mL) and ethanol (3 mL 5 mL). After that, catalyst dried at 60 Ãâ¹Ã
¡C and reused in the reductive amination reaction with a fresh reaction substances. It might be noted that after each run, a slight amount of the catalysts were lost in the filtration process. Herein, to overcome this problem, after each experiment the amount of remaining catalyst was specified and the molar ratio of the reactants was adjusted according to the remaining amount of the catalyst. The catalyst was reused up to 5 times. The catalyst that react in acetonitrile solvent have serious loss activity. In further investigation, it recognized that the catalyst used in acetonitrile solvent was somewhat destroyed. It can be attributed to the interaction between acetonitrile as a solvent and PVSA/CMK-3 composite. In other cases, not o nly the reusability of the catalyst that performed in water was adequate, but also the catalyst exhibit high stability in this status. This result obtained by SEM and XRD characterization, which can be seen in Figure 9 and 10. As shown in SEM images of reused catalyst in water as reaction solvent is well retained, which is very essential for the catalyst applications. Similarly, the XRD pattern shows a diffraction peak at low angle (1.04Ã °). It display that the catalyst structure remain. Because of this fact that the reusability in the heterogeneous catalysts is fundamental, water in reductive amination reaction chosen as a compatible solvent. The catalytic activity of the Ni/PVSA/CMK-3 in the reductive amination was compared with CMK-3, PVSA/CMK-3, and without a catalyst. The results are available in Table 6. The consequences affirm the significance role of the acid-metal heterogeneous catalyst in sort of reaction. As shown, the reaction dose not fulfil up to 5% without catalyst. There is the important issue that NaBH4 function as a mild hydride donor agent, which is incapable reagent for reducing imine groups solely. In a similar manner, this result obtained by using CMK-3 due to the fact that mesoporous carbon CMK-3 does not have any active sites to carry out the reaction. By using the PVSA/CMK-3, with improve acidic feature of the mesoporous carbon the carbonyl group activated and thus the yield moderately increased to 40% and 35% in acetonitrile and water solvent, respectively. In addition, using Ni/PVSA/CMK-3, the reaction efficiency was increased to 97% in 35 and 63 min in acetonitrile and water solvent, respectivel y; Because of the role of nickel nanoparticles as species to transfer hydride ions from NaBH4 to imine groups. The interesting point in catalyst investigation is heterogeneous nature. In this regard, the catalyst was separated from the reaction mixture at approximately 50% conversion of the starting substances by filtration and then centrifugation. The reaction progress in the filtrate circumstance was monitored (data not shown). No further reductive amination reaction occurred even at addition times, representing that the nature of reaction process is heterogeneous and there is not any progress for the reaction in homogeneous phase.
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